Yes, you can.
Within Payoneer, there is a system to make payment to any other Payoneer user. You have to know the email address of the Payoneer user – the one to which their account is tied into.
Simply ask the other party to go to the “Pay” option and select “Make a Payment” option from the main menu.
From there, ask them to fill out this section:
It is as simple as that. It takes an hour or two if this is the first time you’re doing this and from there on, depending on the amount, it is usually completed in a few minutes.